A fire destroyed the Greek School that had been built thanks to a donation from Dem. Zamanis. The library, containing 4000 books and manuscripts, was razed. After the incident, the school operated in the cells of the church of Aghia Paraskevi.
In the 19th century, Metsovo had five schools: one nursery school, one girls’ school, two primary schools (the central one and that of Aghios Demetrios) and one secondary school consisting of two classrooms.